Catalysts

Rh

homogamous catalyst

Code

Name

Formula

CAS

Color & Form

Precious Metal Content (wt%)

K301

Chlorotris(triphenylphosphine)rhodium (wilkinson's catalyst)

RhCl(PPh3)3

14694-95-2

magenta crystals

11.1

K302

Acetylacetonatocarbonyltriphenylphosphinerhodium  (ROPAC)

Rh(acac)(CO)(PPh3)

25470-96-6

yellow crystals

20.9

K303

Acetylacetonatodicarbonylrhodium(I)     (CARAC)

Rh(acac)(CO)2

14874-82-9

green flaky crystals

39.9

K304

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

[Rh(COD)2]BF

35138-22-8

dark red

25.3

K305

Di(µ-chloro)bis(cycloocta- 1,5-diene)dirhodium(I)

Rh2Cl2(COD)2

12092-47-6

orange crystals

41.7

K306

Di(µ-chloro)tetrakis( ethylene)dirhodium(I)

Rh2Cl2(C2H4)

12081-16-2

red-brown powder

52.9

K307

Hydridotetrakis(triphenylphosphine)rhodium(I)

RhH(PPh3)

18284-36-1

yellow powder

8.9

K308

Rhodium Iodide

RhI3

15492-38-3

black crystalline powder

21

K309

Rhodium trichloride hydrate

RhCl3.nH2O

10049-07-7

red-brown crystals

43

K310

Rhodium(II)acetate dimer

[Rh(CH3CO2)2]2

15956-28-2

emerald green powder

46.6

K311

Rhodium(II)octanoate dimer

[Rh(C8H15O2)2]2

73482-96-9

emerald green powder

26.4

K312

Rhodium(II)trifluoroacetatedimer

[Rh(CF3CO2)2]2

31126-95-1

green powder

31.3

K313

Tris(ethylenediamine)rhodium(III) chloride hydrate

Rh(acac)3

14284-92-5

yellow crystals

25.7

K314

Tris(acetylacetonato)rhodium(III)

[Rh(C2H8N2)3]Cl3.3H2O

14023-02-0

white needles

23

K315

Carbonylchlorobis(triphenylphosphine)rhodium(I)

RhCl(CO)(PPh3)2

13938-94-8 red powder 22
K316

Carbonyltris(triphenylphosphine)rhodium(I)hydride

RhH(CO)(PPh3)3

17185-29-4

yellow powder

11
K317

Rhodium acetate

[Rh(OAc)2]2

42204-14-8

26105-49-7

brown  crystals

39
K318

Rhodium (III)chloride hydrate

RhCl3.nH2O

20765-98-4

red  crystals

39
K319

Acetylacetonato(1,5-cyclooctadiene)rhodium

Rh(COD)(acac)

12245-39-5

yellow powder

33
K320

Bis(1,5-cyclooctadiene)rhodium trifluoromethanesulfonate

Rh(COD)2SO3CF3

99326-34-8

red powder

22
K321

Acetylacetonatobis(ethylene)rhodium

Rh(C2H4)2(acac)

12082-47-2

 brownish yellow powder

39.9
K322

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

[RhCl2C10H15]2

12354-85-7

red wine crystals

33.3
K323

Trisodium hexachlororhodate

Na3RhCl6

14972-70-4

rose red crystals

26.8
K324

Tripotassium hexachlororhodate

K3RhCl6

13845-07-3

rose red crystals

23.8
K325

Ammonium hexachlororhodate

(NH4)3.RhCl6

15336-18-2

reddish brown crystals

27.8
K326

(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodate

C36H40BF4O2P2Rh

56977-92-5 13.6
K327

Chloro(dioxygen)bis(triphenylphosphine)rhodium

Rh(Cl)(O2)(Ph3P)2

brown crystals

14.8
K328

Trisodium hexachlororhodate hydrate

Na3RhCl6.nH2O

15002-93-3

rose red

~20
K329

Dis-chloro-bis[dicarbonylrhodium]

[RhCl(CO)2]2

14404-25-2

red crystals

52.9
K330

Di-?propionato-bis propionatorhodium

[Rh(C3H5O2)(?C3H5O2)]2

31126-81-5

green powder

41
K331

Hexaamminerhodium trichloride

(NH3)6.RhCl3

13820-96-7

white crystals

33
K332

Pentaamminechlororhodium(III) dichloride

[RhCl(NH3)5]Cl2

13820-95-6

yellow powder

34.5
K333

Bis(norbornadiene)rhodium(I) tetrafluoroborate

[Rh(nbd)2]BF4

36620-11-8

red powder

27
K334

Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate

[Rh(COD)2]PF6

62793-31-1

red powder

22
K335

Di-?chlorobis(norbornadiene) dirhodium(I)

[Rh(nbd)2]Cl2

12257-42-0

yellow powder

45
K336

Rhodium(III) sulfate

Rh2(SO4)3

10489-46-0

brown powder

41.7
K337

Rhodium(?) phosphate

RhPO4

67859-71-6

yellow or red powder

52
K338

Rhodium(?) nitrate hydrate

Rh(NO3)3.nH2O

13465-43-5

brown

40
K339

Rhodium(?) nitrate solution

Rh(NO3)3

10139-58-9

brown solution

1-12
K340

Rhodium(III) sulfite

Rh2(SO3)3

white crystals

48.4
K341

Rhodium trihydroxide

Rh2O3?H2O

21656-02-0

yellow powder

55
K342

Rhodium hydroxide

Rh(OH)3

123542-79-0

yellow powder

66.9
K343

Bromotris(triphenylphosphine)rhodium

RhBr(PPh3)3

14973-89-8

red crystals

10.6
K344

Dodecacarbonyltetrarhodium

[Rh4(CO)12]

19584-30-6

orange powder

55.1
K345

Hexadecacarbonylhexarhodium

Rh6(C0)16

28407-51-4

black powder

57.5
K346

Chlorodicarbonylrhodium dimmer

[Rh(C0)2Cl]2

14523-22-9

orange crystals

52.9
K347

Chlorobis(ethylene)rhodium(I) dimer

[Rh(C2H4)2Cl]2

12081-16-2

reddish brown powder

52.9
K348

Rhodium tris(2-ethylhexanoate)

Rh(C8H15O2)3

20845-92-5

reddish brown powder

19.3
K349

Rhodium black

Rh

7440-16-6

black powder

99.95

HETEROGENEOUS CATALYSTS

Code

Name

Support Material

Precious Metal Content (wt%)

K381

Rh/C

Active Carbon

1% 5% 10% 20%

K382

Rh/SiO2

SiO2

1% 2% 5% 10%

K383

Rh/Al2O3

Al2O3

1% 5% 10% 20%

TOP

Pt

homogamous catalyst

Code

Name

Formula

CAS

Color & Form

Precious Metal Content (wt%)

K501

Adams Catalyst

PtO2.xH2O

1314-15-4

Black. Powders

79.6

K502

Ammonium chloroplatinite

(NH4)2[PtCl4]

13820-41-2

Yellow Powder

52

K503

Chloroplatinic acid crystal

H2[PtCl6].nH2O

16941-12-1

Red Crystal

39-42

K504 cis-diamminediChlorideplatinum cis-[Pt(NH3)2]Cl2

15663-27-1

orange powder

65

K505

cis-Dichlorobis(triphenylphosphine)platinum(II)

cis-PtCl2(PPh3)2

15672-07-6

white crystals

24.7

K506

Cis-dichlorobis(triphenylphosphite)platinum(II)

Pt[P(OPh)3]2Cl2

30053-58-8

yellow crystals

22

K507

Dichloro(1,5-cyclooctadiene)platinum(II)

PtCl2(COD)

12080-32-9

white to pale powder

52.1

K508

Diphenyl(1,5-cyclooctadiene)platinum(II)

Pt(COD)(C6H5)2

12277-88-2

yellow powde

42.6

K509

Potassium hexachloroplatinate

K2[PtCl6]

16921-30-5

Yellow Powder

40

K510

Potassium tetrachloroplatinite (II)

K2[PtCl4]

10025-99-7

Red Powder

46

K511

Tetrakis(triphenylphosphine)platinum(0)

Pt(PPh3)4

14221-02-4

pale yellow

15.7

K512

Trans-diamminedichloroplatinum(II)

trans-[Pt(NH3)2Cl2]

14913-33-8

orange powder

65

K513 Bis(benzonitrile)dichloroplatinum(II) PtCl2(PhCN)2 15617-19-3 green powder 41
K514 Ammonium chloroplatinate (NH4)2[PtCl6] 16919-58-7 yellow powder 44
K515 Dibromo(1,5-cyclooctadiene)platinum(II) PtBr2(COD) 12145-48-1 yellow powder 42
K516 Platinum tetrachloride PtCl4 13454-96-1 red brown crystals 58
K517 Dihydrogen hexahydroxoplatinate H2Pt(OH)6 51850-20-5 yellow solution 1-10
K518 Sodium hexahydroxoplatinate Na2Pt(OH)6 12325-31-4 yellow powder 56
K519 Potassium hexahydroxoplatinate K2Pt(OH)6 12285-90-4 yellow powder 52
K520 Tetraammineplatinum Chloride      (TPC Pt) [Pt(NH3)4]Cl2 16971-49-6 white solution 1-6
K521 Sodium tetrachloroplatinate(?) Na2PtCl4 10026-00-3 red solution ~8
K522 Tetraammineplatinum hydroxide solution    (TPH Pt) [Pt(NH3)4](OH)2 38201-97-7 white solution ~10
K523 Tetraammineplatinum hydroxide nitrate   (TPN Pt) [Pt(NH3)4](NO3)2 20634-12-2 pale yellow solution ~3
K524 cis-Dichlorobis(triphenylphosphine)platinum(II) cis-PtCl2(PPh3)2 10199-34-5 white crystals 24.7
K525 Tetraammineplatinum hydrogenphosphate solution [Pt(NH3)4]HPO4 127733-98-6 white solution ~2
K526 Tetraammineplatinum hydrogencarbonate      (TPHC Pt) [Pt(NH3)4](HCO3)2 123439-82-7 white powder 51
K527 Di-mu-chlorobis[chloro(cyclohexene)platinum(II)] [PtCl(C6H10)]2Cl2 12176-53-3 pale yellow crystals 55
K528 Dinitrosulfato Platinum (II)      (Pt DNS) H2[Pt(NO2)2](SO3)2 68958-85-0 yellow solution 1-5
K529 Divinyltetramethyldisiloxane complex  (Karstedt catalyst) O[Si(CH3)2CHCH2]2Pt 68478-92-2 pale yellow solution 0.1-5
K530 Tetraammineplatinum Chloride [Pt(NH3)4]Cl2?2O 13933-32-9 pale yellow crystals 55
K531 Potassium Trichlorammine Platinum (II) K[PtCl3(NH3)] 13820-91-2 orange crystals 51.9
K532 cis-Diamminediiodoplatinum(II) cis-[PtI2(NH3)2] 15978-93-5 green brown powder 40
K533 cis-Dibromobis(triphenylphosphite)platinum(II). PtBr2(P(OPh)3)2 41871-81-2 yellow powder 20
K534 Platinum nitrate Pt(NO3)3 18496-40-7 brown yellow solution 1-10
K535 Sodium hexachloroplatinate(?) hydrate solution Na2PtCl6.nH2O 19583-77-8 red solution 1-15
K536 Potassium tetranitroplatinate(II) K2Pt(NO2)4 13815-39-9 white crystals 42
K537 Platinum diaminodinitrite [Pt(NH3)2](NO2)2 14286-02-3 white powder 59
K538 Platinum sulfite solution Pt(SO3)x 61420-92-6 yellow solution 1-10
K539 Hexachloroplatinum(?) Acid Hydrate H2PtCl6?H2O 26023-84-7 red solution 1-10
K540 Bis (acetylacetonato) platinum (II) Pt(acac)2 15170-57-7 yellow powder 49
K541 Platium chlorde PtCl2 10025-65-7 brown powder 73.6
K542 Platinum(IV) oxide hydrate PtO2.nH2O 52785-06-5 black powder 79.6
K543 Platinum black Pt 7440-06-4 black powder 99.95

HETEROGENEOUS CATALYSTS

Code

Name

Support Material

Precious Metal Content (wt%)

K581

Pt/C

Active Carbon

1% 5% 10% 20%

K582

Pt/SiO2

SiO2

1% 2% 5% 10%

K583

Pt/Al2O3

Al2O3

1% 5% 10% 20%

 

PLATINUM COMPOUNDS FOR ANTI-TUMOR

 

Code

Name

Chemical Name

Formula

CAS

Color & Form

Standard

K591

cisplatin

Cis-Diammine dichloroplatinum

Cl2H6N2Pt

15663-27-1

yellow microcrystalline powder

USP26 EP4

K592

carbonplatin

Cis-Diammine(1,1-cyclobutanedicarboxylato)platinum

C6H12N2O4Pt

41575-94-4

white microcrystalline powder

USP26 EP4

K593

oxaliplatin

Cis-[(1R,2R)-1,2-cyclothexanediammine-N,N`][oxalato(2-)-O,O`]platinum

C8H14N2O4Pt

61825-94-3

white crystalline powder

EP4

TOP

Pd

homogamous catalyst

Code

Name

Formula

CAS

Color & Form

Precious Metal Content (wt%)

K601

Tetrakis(triphenylphosphine)palladium(0)

Pd(PPh3)4

14221-01-3

yellow crystal

9.2

K602

Bis(acetylacetonato)palladium(II)

Pd(acac)2

14024-61-4

orange crystal

34.9

K603

Diacetatobis(triphenylphosphine)palladium(II)

Pd(OAc)2(PPh3)2

14588-08-0

yellow powder

14.2

K604

Dichloro(1,5-cyclooctadiene)palladium(II)

Pd(COD)Cl2

12107-56-1

yellow powder

37.3

K605

Palladium(II)acetate trimer

[Pd(OAc)2]3

3375-31-3

brown needle crystal

47.4

K606

Tetramminepalladium(II)chloride

[Pd(NH3)4]Cl2.H2O

13815-17-3

yellow powder

41

K607

trans-Bis(benzonitrile)dichloropalladium(II)

trans-PdCl2(PhCN)2

14220-64-5

yellow powder

27.7

K608

Trans-diamminedichloropalladium(II)

trans-[Pd(NH3)2Cl2]

13782-33-7

yellow powder

50

K609

Bis(tri-t-butylphosphine)palladium(0)

Pd[P(t-Bu)3]2

53199-31-8

white crystal

21.0

K610

Dichloro(1,2-bis(diaphenylphosphino)ethane)palladium(II)

PdCl2(dppe)

19978-61-1

orange powder

18.5

K611

Trans-dichlorobis(triphenylphosphine)palladium(II)

trans-PdCl2(PPh3)2

13965-03-2

yellow powder

15.2

K612

Tris(dibenzylideneacetone)dipalladium(0)

Pd2(C17H14O)3

51364-51-3

purple solid

23.2

K613

Palladium(II) Chloride

PdCl2

7647-10-1

brown powder

60.0

K614

Palladium(II) trifluoroacetate

Pd(CF3CO2)2

42196-31-6

light brown  crystal

32

K615 Tetraamminepalladium(II) nitrate [Pd(NH3)4](NO3)2 13601-08-6 pale yellow crystal 35
K616 [1,3-Bis(diphenylphosphino)propane] palladium(II) Dihloride PdCl2(dppp) 59831-02-6 off-white crystal 18
K617 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf).CH2Cl2 95464-05-4 red crystal 13
K618 Tetraamminepalladium(II) sulfate [Pd(NH3)4]SO4 13601-06-4 yellow powder 40
K619 Tetraamminepalladium(II) hydrogen carbonate [Pd(NH3)4](HCO3)2 134620-00-1 cream crystal 35
K620 Tetraamminepalladium(II)hydroxide [Pd(NH3)4](OH)2 68413-68-3 yellow solution 1-10
K621 Tetraamminepalladium(II) acetate [Pd(NH3)4](OAc)2 61495-96-3 yellow solution 5~
K622 Dichlorobis(tricyclohexylphosphine)palladium [(C6H11)3P]2PdCl2 29934-17-6 pale yellow powder 14.4
K623 Potassium tetrabromopalladate K2PdBr4 13826-93-2 reddish brown  crystal 21.1
K624 Bis(ethylenediamine)palladium(II) chloride Pd(en)2Cl2 13963-53-6 yellow crystal 44.7
K625 Diaminedinitritopalladium Pd(NH3)2(NO2)2 14708-52-2 yellow crystal 45.6
K626 1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladium(II) PdCl2(dppf) 72287-26-4 red crystal 13
K627 Tris(dibenzylideneacetone)dipalladium Pd2(dba)3 52409-22-0 reddish brown powder 20
K628 Tetraamminepalladium (II) chloride Pd(NH3)4Cl2 13933-31-8 yellow powder 42
K629 Palladium sulfate PdSO4 13566-03-5 brown solution -12
K630 Palladium dinitrate Pd(NO3)2?H2O 10102-05-3 yellowish brown 41
K631 Sodium tetrachloropalladate Na2PdCl4 13820-53-6 brown solution 1-10
K632 Ammonium hexachloropalladate (NH4)2PdCl6 19168-23-1  brown crystal 30
K633 Ammonium tetrachloropalladate (NH4)2PdCl4 13820-40-1 green crystal 37
K634 Palladium Chloride PdCl2.2H2O 7647-10-1 brown powder 60
K635 Palladium bromide PdBr2 13444-94-5 violet crystal 40
K636 Palladium iodide PdI2 7790-38-7 black powder 29.4
K637 (pi-allyl)Palladium(II)chloridedimer [(pi-C3H5)PdCl]2 12012-95-2 yellow  crystal 58.2
K638 Trans-dichlorobis(acetonitrile)palladium(II) trans-PdCl2(CH3CN)2 14592-56-4 yellow powder 41
K639 Potassium tetrachloropalladate K2PdCl4 10025-98-6 brown powder 32
K640 Potassium hexachloropalladate K2PdCl6 16919-73-6 red powder 27
K641 Bis(dibenzylideneacetone)palladium (dba)2Pd 32005-36-0 reddish brown powder 20
K642 Palladium black Pd 7440-05-3 black powder 99.95

HETEROGENEOUS CATALYSTS

Code

Name

Support Material

Precious Metal Content (wt%)

K681

Pd/C

Active Carbon

1% 5% 10% 20%

K682

Pd/SiO2

SiO2

1% 2% 5% 10%

K683

Pd/Al2O3

Al2O3

1% 5% 10% 20%

K684 Pd(OH)2/C Active Carbon 1% 5% 10% 20%
K685 Pd/BaSO4 BaSO4 1% 5% 10% 20%
K686 LINDLAR  Pd/CaO3 CaO3 1% 5% 10% 20%

TOP

Ru

homogamous catalyst

Code

Name

Formula

CAS

Color & Form

Precious Metal Content (wt%)

K201 Ruthenium trichloride RuCl3 10049-08-8 brown powder 49
K202 Ruthenium trichloride RuCl3.nH2O 14898-67-0 brownish black crystals 40
K203 Ruthenium acetate Ru(OAc)x 55466-76-7 black powder 47
K204 Ruthenium oxide RuO2 12036-10-1 black powder 75
K205 Ruthenium oxide hydrate RuO2.nH2O 32740-79-7 black powder 62
K206 Tris(triphenylphosphine)Rutheniumdichloride RuCl2(PPh3)3 15529-49-4 reddish brown  crystals 10
K207 (1,5-Cyclooctadiene)-dichloro Ruthenium Ru(COD)Cl2 50982-12-2 brown powder 35
K208 Carbonyltris(triphenylphosphine)rhodium(I)dihydride RuH2(CO)(PPh3)3 25360-32-1 cream powder 11
K209 TrisacetylacetonateRuthenium Ru(acac)3 14284-93-6 red powder 25
K210 Ammonium hexachloroRuthenate(IV) (NH4)2[RuCl6] 18746-63-9 brown powder 31
K211 Ammonium-nitrido-octachlorodiaquodiruthenate(IV) (NH4)3.Cl8H4NO2Ru2 27316-90-1 red powder 34
K212 Dichloro(p-cymene)ruthenium(II) dimer Ru(C10H14)2Cl2 52462-29-0 brown  crystals 33
K213 Ruthenium nitrosyl nitrate Ru(NO3)3.NO 34513-98-9 reddish brown powder 30

HETEROGENEOUS CATALYSTS

Code

Name

Support Material

Precious Metal Content (wt%)

K281

Ru/C

Active Carbon

1% 5% 10% 20%

K282

Ru/SiO2

SiO2

1% 2% 5% 10%

K283

Ru/Al2O3

Al2O3

1% 5% 10% 20%

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