|
Rh |
|||||
|
homogamous
catalyst |
|||||
|
Code |
Name |
Formula |
CAS |
Color & Form |
Precious
Metal Content (wt%) |
|
Chlorotris(triphenylphosphine)rhodium |
RhCl(PPh3)3 |
14694-95-2 |
magenta crystals |
11.1 |
|
|
Acetylacetonatocarbonyltriphenylphosphinerhodium
( |
Rh(acac)(CO)(PPh3) |
25470-96-6 |
yellow
crystals |
20.9 |
|
|
Acetylacetonatodicarbonylrhodium(I) |
Rh(acac)(CO)2 |
14874-82-9 |
green flaky
crystals |
39.9 |
|
|
Bis(1,5-cyclooctadiene)rhodium(I)
tetrafluoroborate |
[Rh(COD)2]BF |
35138-22-8 |
dark red |
25.3 |
|
|
Di(µ-chloro)bis(cycloocta- 1,5-diene)dirhodium(I) |
Rh2Cl2(COD)2 |
12092-47-6 |
orange
crystals |
41.7 |
|
|
Di(µ-chloro)tetrakis( ethylene)dirhodium(I) |
Rh2Cl2(C2H4) |
12081-16-2 |
red-brown
powder |
52.9 |
|
|
Hydridotetrakis(triphenylphosphine)rhodium(I) |
RhH(PPh3) |
18284-36-1 |
yellow powder |
8.9 |
|
|
Rhodium Iodide |
RhI3 |
15492-38-3 |
black crystalline powder |
21 |
|
|
Rhodium
trichloride hydrate |
RhCl3.nH2O |
10049-07-7 |
red-brown
crystals |
43 |
|
|
Rhodium(II)acetate
dimer |
[Rh(CH3CO2)2]2 |
15956-28-2 |
emerald green
powder |
46.6 |
|
|
Rhodium(II)octanoate
dimer |
[Rh(C8H15O2)2]2 |
73482-96-9 |
emerald green powder |
26.4 |
|
|
Rhodium(II)trifluoroacetatedimer |
[Rh(CF3CO2)2]2 |
31126-95-1 |
green |
31.3 |
|
|
Tris(ethylenediamine)rhodium(III)
chloride hydrate |
Rh(acac)3 |
14284-92-5 |
yellow
crystals |
25.7 |
|
|
Tris(acetylacetonato)rhodium(III) |
[Rh(C2H8N2)3]Cl3.3H2O |
14023-02-0 |
white needles |
23 |
|
|
Carbonylchlorobis(triphenylphosphine)rhodium(I) |
RhCl(CO)(PPh3)2 |
13938-94-8 | red powder | 22 | |
|
Carbonyltris(triphenylphosphine)rhodium(I)hydride |
RhH(CO)(PPh3)3 |
17185-29-4 |
yellow powder |
11 | |
|
Rhodium acetate |
[Rh(OAc)2]2 |
42204-14-8 26105-49-7 |
brown crystals |
39 | |
|
Rhodium (III)chloride hydrate |
RhCl3.nH2O |
20765-98-4 |
red crystals |
39 | |
|
Acetylacetonato(1,5-cyclooctadiene)rhodium |
Rh(COD)(acac) |
12245-39-5 |
yellow powder |
33 | |
|
Bis(1,5-cyclooctadiene)rhodium trifluoromethanesulfonate |
Rh(COD)2SO3CF3 |
99326-34-8 |
red powder |
22 | |
|
Acetylacetonatobis(ethylene)rhodium |
Rh(C2H4)2(acac) |
12082-47-2 |
brownish yellow powder |
39.9 | |
|
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] |
[RhCl2C10H15]2 |
12354-85-7 |
red wine crystals |
33.3 | |
|
Trisodium hexachlororhodate |
Na3RhCl6 |
14972-70-4 |
rose red crystals |
26.8 | |
|
Tripotassium hexachlororhodate |
K3RhCl6 |
13845-07-3 |
rose red crystals |
23.8 | |
|
Ammonium hexachlororhodate |
(NH4)3.RhCl6 |
15336-18-2 |
reddish brown crystals |
27.8 | |
|
(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodate |
C36H40BF4O2P2Rh |
56977-92-5 | 13.6 | ||
|
Chloro(dioxygen)bis(triphenylphosphine)rhodium |
Rh(Cl)(O2)(Ph3P)2 |
brown crystals |
14.8 | ||
|
Trisodium hexachlororhodate hydrate |
Na3RhCl6.nH2O |
15002-93-3 |
rose red |
~20 | |
|
Dis-chloro-bis[dicarbonylrhodium] |
[RhCl(CO)2]2 |
14404-25-2 |
red
crystals |
52.9 | |
|
Di-?propionato-bis propionatorhodium |
[Rh(C3H5O2)(?C3H5O2)]2 |
31126-81-5 |
green powder |
41 | |
|
Hexaamminerhodium trichloride |
(NH3)6.RhCl3 |
13820-96-7 |
white crystals |
33 | |
|
Pentaamminechlororhodium(III) dichloride |
[RhCl(NH3)5]Cl2 |
13820-95-6 |
yellow powder |
34.5 | |
|
Bis(norbornadiene)rhodium(I) tetrafluoroborate |
[Rh(nbd)2]BF4 |
36620-11-8 |
red powder |
27 | |
|
Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate |
[Rh(COD)2]PF6 |
62793-31-1 |
red powder |
22 | |
|
Di-?chlorobis(norbornadiene) dirhodium(I) |
[Rh(nbd)2]Cl2 |
12257-42-0 |
yellow powder |
45 | |
|
Rhodium(III) sulfate |
Rh2(SO4)3 |
10489-46-0 |
brown powder |
41.7 | |
|
Rhodium(?) phosphate |
RhPO4 |
67859-71-6 |
yellow or red powder |
52 | |
|
Rhodium(?) nitrate hydrate |
Rh(NO3)3.nH2O |
13465-43-5 |
brown |
40 | |
|
Rhodium(?) nitrate solution |
Rh(NO3)3 |
10139-58-9 |
brown solution |
1-12 | |
|
Rhodium(III) sulfite |
Rh2(SO3)3 |
white crystals |
48.4 | ||
|
Rhodium trihydroxide |
Rh2O3?H2O |
21656-02-0 |
yellow powder |
55 | |
|
Rhodium hydroxide |
Rh(OH)3 |
123542-79-0 |
yellow powder |
66.9 | |
|
Bromotris(triphenylphosphine)rhodium |
RhBr(PPh3)3 |
14973-89-8 |
red
crystals |
10.6 | |
|
Dodecacarbonyltetrarhodium |
[Rh4(CO)12] |
19584-30-6 |
orange powder |
55.1 | |
|
Hexadecacarbonylhexarhodium |
Rh6(C0)16 |
28407-51-4 |
black powder |
57.5 | |
|
Chlorodicarbonylrhodium dimmer |
[Rh(C0)2Cl]2 |
14523-22-9 |
orange crystals |
52.9 | |
|
Chlorobis(ethylene)rhodium(I) dimer |
[Rh(C2H4)2Cl]2 |
12081-16-2 |
reddish brown powder |
52.9 | |
|
Rhodium tris(2-ethylhexanoate) |
Rh(C8H15O2)3 |
20845-92-5 |
reddish brown powder |
19.3 | |
|
Rhodium black |
Rh |
7440-16-6 |
black powder |
99.95 | |
|
HETEROGENEOUS
CATALYSTS |
|||||
|
Code |
Name |
Support
Material |
Precious Metal Content (wt%) |
||
| K381 |
Rh/C |
Active Carbon |
1% 5% 10% 20% |
||
| K382 |
Rh/SiO2 |
SiO2 |
1% 2% 5% 10% |
||
| K383 |
Rh/Al2O3 |
Al2O3 |
1% 5% 10% 20% |
||
|
Pt |
|||||
|
homogamous
catalyst |
|||||
|
Code |
Name |
Formula |
CAS |
Color & Form |
Precious
Metal Content (wt%) |
|
|
PtO2.xH2O |
1314-15-4 |
Black. Powders |
79.6 |
|
|
Ammonium
chloroplatinite |
(NH4)2[PtCl4] |
13820-41-2 |
Yellow Powder |
52 |
|
|
Chloroplatinic acid crystal |
H2[PtCl6].nH2O |
16941-12-1 |
Red
|
39-42 |
|
| cis-diamminediChlorideplatinum | cis-[Pt(NH3)2]Cl2 |
15663-27-1 |
orange powder |
65 |
|
|
cis-Dichlorobis(triphenylphosphine)platinum(II) |
cis-PtCl2(PPh3)2 |
15672-07-6 |
white crystals |
24.7 |
|
|
Cis-dichlorobis(triphenylphosphite)platinum(II) |
Pt[P(OPh)3]2Cl2 |
30053-58-8 |
|
22 |
|
|
Dichloro(1,5-cyclooctadiene)platinum(II) |
PtCl2(COD) |
12080-32-9 |
white to pale powder |
52.1 |
|
|
Diphenyl(1,5-cyclooctadiene)platinum(II) |
Pt(COD)(C6H5)2 |
12277-88-2 |
|
42.6 |
|
|
Potassium
hexachloroplatinate |
|
16921-30-5 |
Yellow Powder |
|
|
|
Potassium
tetrachloroplatinite (II) |
|
10025-99-7 |
Red Powder |
|
|
|
Tetrakis(triphenylphosphine)platinum(0) |
Pt(PPh3)4 |
14221-02-4 |
pale yellow |
15.7 |
|
|
Trans-diamminedichloroplatinum(II) |
trans-[Pt(NH3)2Cl2] |
14913-33-8 |
orange powder |
65 |
|
| Bis(benzonitrile)dichloroplatinum(II) | PtCl2(PhCN)2 | 15617-19-3 | green powder | 41 | |
| Ammonium chloroplatinate | (NH4)2[PtCl6] | 16919-58-7 | yellow powder | 44 | |
| Dibromo(1,5-cyclooctadiene)platinum(II) | PtBr2(COD) | 12145-48-1 | yellow powder | 42 | |
| Platinum tetrachloride | PtCl4 | 13454-96-1 |
red brown crystals |
58 | |
| Dihydrogen hexahydroxoplatinate | H2Pt(OH)6 | 51850-20-5 | yellow solution | 1-10 | |
| Sodium hexahydroxoplatinate | Na2Pt(OH)6 | 12325-31-4 | yellow powder | 56 | |
| Potassium hexahydroxoplatinate | K2Pt(OH)6 | 12285-90-4 | yellow powder | 52 | |
| Tetraammineplatinum Chloride (TPC Pt) | [Pt(NH3)4]Cl2 | 16971-49-6 | white solution | 1-6 | |
| Sodium tetrachloroplatinate(?) | Na2PtCl4 | 10026-00-3 | red solution | ~8 | |
| Tetraammineplatinum hydroxide solution (TPH Pt) | [Pt(NH3)4](OH)2 | 38201-97-7 | white solution | ~10 | |
| Tetraammineplatinum hydroxide nitrate (TPN Pt) | [Pt(NH3)4](NO3)2 | 20634-12-2 | pale yellow solution | ~3 | |
| cis-Dichlorobis(triphenylphosphine)platinum(II) | cis-PtCl2(PPh3)2 | 10199-34-5 |
white crystals |
24.7 | |
| Tetraammineplatinum hydrogenphosphate solution | [Pt(NH3)4]HPO4 | 127733-98-6 | white solution | ~2 | |
| Tetraammineplatinum hydrogencarbonate (TPHC Pt) | [Pt(NH3)4](HCO3)2 | 123439-82-7 | white powder | 51 | |
| Di-mu-chlorobis[chloro(cyclohexene)platinum(II)] | [PtCl(C6H10)]2Cl2 | 12176-53-3 |
pale yellow crystals |
55 | |
| Dinitrosulfato Platinum (II) (Pt DNS) | H2[Pt(NO2)2](SO3)2 | 68958-85-0 | yellow solution | 1-5 | |
| Divinyltetramethyldisiloxane complex (Karstedt catalyst) | O[Si(CH3)2CHCH2]2Pt | 68478-92-2 | pale yellow solution | 0.1-5 | |
| Tetraammineplatinum Chloride | [Pt(NH3)4]Cl2?2O | 13933-32-9 |
pale yellow crystals |
55 | |
| Potassium Trichlorammine Platinum (II) | K[PtCl3(NH3)] | 13820-91-2 |
orange crystals |
51.9 | |
| cis-Diamminediiodoplatinum(II) | cis-[PtI2(NH3)2] | 15978-93-5 | green brown powder | 40 | |
| cis-Dibromobis(triphenylphosphite)platinum(II). | PtBr2(P(OPh)3)2 | 41871-81-2 | yellow powder | 20 | |
| Platinum nitrate | Pt(NO3)3 | 18496-40-7 | brown yellow solution | 1-10 | |
| Sodium hexachloroplatinate(?) hydrate solution | Na2PtCl6.nH2O | 19583-77-8 | red solution | 1-15 | |
| Potassium tetranitroplatinate(II) | K2Pt(NO2)4 | 13815-39-9 |
white crystals |
42 | |
| Platinum diaminodinitrite | [Pt(NH3)2](NO2)2 | 14286-02-3 | white powder | 59 | |
| Platinum sulfite solution | Pt(SO3)x | 61420-92-6 | yellow solution | 1-10 | |
| Hexachloroplatinum(?) Acid Hydrate | H2PtCl6?H2O | 26023-84-7 | red solution | 1-10 | |
| Bis (acetylacetonato) platinum (II) | Pt(acac)2 | 15170-57-7 | yellow powder | 49 | |
| Platium chlorde | PtCl2 | 10025-65-7 | brown powder | 73.6 | |
| Platinum(IV) oxide hydrate | PtO2.nH2O | 52785-06-5 | black powder | 79.6 | |
| Platinum black | Pt | 7440-06-4 | black powder | 99.95 | |
|
HETEROGENEOUS
CATALYSTS |
|||||
|
Code |
Name |
Support Material |
Precious Metal
Content (wt%) |
||
| K581 |
Pt/C |
Active Carbon |
1% 5% 10% 20% |
||
| K582 |
Pt/SiO2 |
SiO2 |
1% 2% 5% 10% |
||
| K583 |
Pt/Al2O3 |
Al2O3 |
1% 5% 10% 20% |
||
|
PLATINUM
COMPOUNDS FOR ANTI-TUMOR |
|
Code |
Name |
Chemical Name |
Formula |
CAS |
Color & Form |
Standard |
| K591 |
cisplatin |
Cis-Diammine
dichloroplatinum |
Cl2H6N2Pt |
15663-27-1 |
yellow
microcrystalline powder |
USP26 EP4 |
| K592 |
carbonplatin |
Cis-Diammine(1,1-cyclobutanedicarboxylato)platinum |
C6H12N2O4Pt |
41575-94-4 |
white
microcrystalline powder |
USP26 EP4 |
| K593 |
oxaliplatin |
Cis-[(1R,2R)-1,2-cyclothexanediammine-N,N`][oxalato(2-)-O,O`]platinum |
C8H14N2O4Pt |
61825-94-3 |
white
crystalline powder |
EP4 |
|
Pd |
|||||
|
homogamous
catalyst |
|||||
|
Code |
Name |
Formula |
CAS |
Color & Form |
Precious
Metal Content (wt%) |
| K601 |
Tetrakis(triphenylphosphine)palladium(0) |
Pd(PPh3)4 |
14221-01-3 |
yellow crystal |
9.2 |
| K602 |
Bis(acetylacetonato)palladium(II) |
Pd(acac)2 |
14024-61-4 |
orange crystal |
34.9 |
| K603 |
Diacetatobis(triphenylphosphine)palladium(II) |
Pd(OAc)2(PPh3)2 |
14588-08-0 |
yellow
powder |
14.2 |
| K604 |
Dichloro(1,5-cyclooctadiene)palladium(II) |
Pd(COD)Cl2 |
12107-56-1 |
yellow
powder |
37.3 |
| K605 |
Palladium(II)acetate
trimer |
[Pd(OAc)2]3 |
3375-31-3 |
brown
needle crystal |
47.4 |
| K606 |
Tetramminepalladium(II)chloride |
[Pd(NH3)4]Cl2.H2O |
13815-17-3 |
yellow
powder |
41 |
| K607 |
trans-Bis(benzonitrile)dichloropalladium(II) |
trans-PdCl2(PhCN)2 |
14220-64-5 |
yellow
powder |
27.7 |
| K608 |
Trans-diamminedichloropalladium(II) |
trans-[Pd(NH3)2Cl2] |
13782-33-7 |
yellow
powder |
50 |
| K609 |
Bis(tri-t-butylphosphine)palladium(0) |
Pd[P(t-Bu)3]2 |
53199-31-8 |
white crystal |
21.0 |
| K610 |
Dichloro(1,2-bis(diaphenylphosphino)ethane)palladium(II) |
PdCl2(dppe) |
|
orange powder |
18.5 |
| K611 |
Trans-dichlorobis(triphenylphosphine)palladium(II) |
trans-PdCl2(PPh3)2 |
13965-03-2 |
yellow
powder |
15.2 |
| K612 |
Tris(dibenzylideneacetone)dipalladium(0) |
Pd2(C17H14O)3 |
51364-51-3 |
purple
solid |
23.2 |
| K613 |
Palladium(II) Chloride |
PdCl2 |
7647-10-1 |
brown
powder |
60.0 |
| K614 |
|
|
42196-31-6 |
|
|
| K615 | Tetraamminepalladium(II) nitrate | [Pd(NH3)4](NO3)2 | 13601-08-6 |
pale yellow
crystal |
35 |
| K616 | [1,3-Bis(diphenylphosphino)propane] palladium(II) Dihloride | PdCl2(dppp) | 59831-02-6 |
off-white
crystal |
18 |
| K617 | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | PdCl2(dppf).CH2Cl2 | 95464-05-4 |
red
crystal |
13 |
| K618 | Tetraamminepalladium(II) sulfate | [Pd(NH3)4]SO4 | 13601-06-4 | yellow powder | 40 |
| K619 | Tetraamminepalladium(II) hydrogen carbonate | [Pd(NH3)4](HCO3)2 | 134620-00-1 |
cream
crystal |
35 |
| K620 | Tetraamminepalladium(II)hydroxide | [Pd(NH3)4](OH)2 | 68413-68-3 | yellow solution | 1-10 |
| K621 | Tetraamminepalladium(II) acetate | [Pd(NH3)4](OAc)2 | 61495-96-3 | yellow solution | 5~ |
| K622 | Dichlorobis(tricyclohexylphosphine)palladium | [(C6H11)3P]2PdCl2 | 29934-17-6 | pale yellow powder | 14.4 |
| K623 | Potassium tetrabromopalladate | K2PdBr4 | 13826-93-2 |
reddish brown crystal |
21.1 |
| K624 | Bis(ethylenediamine)palladium(II) chloride | Pd(en)2Cl2 | 13963-53-6 |
yellow
crystal |
44.7 |
| K625 | Diaminedinitritopalladium | Pd(NH3)2(NO2)2 | 14708-52-2 |
yellow
crystal |
45.6 |
| K626 | 1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladium(II) | PdCl2(dppf) | 72287-26-4 |
red
crystal |
13 |
| K627 | Tris(dibenzylideneacetone)dipalladium | Pd2(dba)3 | 52409-22-0 | reddish brown powder | 20 |
| K628 | Tetraamminepalladium (II) chloride | Pd(NH3)4Cl2 | 13933-31-8 | yellow powder | 42 |
| K629 | Palladium sulfate | PdSO4 | 13566-03-5 | brown solution | -12 |
| K630 | Palladium dinitrate | Pd(NO3)2?H2O | 10102-05-3 | yellowish brown | 41 |
| K631 | Sodium tetrachloropalladate | Na2PdCl4 | 13820-53-6 | brown solution | 1-10 |
| K632 | Ammonium hexachloropalladate | (NH4)2PdCl6 | 19168-23-1 |
brown
crystal |
30 |
| K633 | Ammonium tetrachloropalladate | (NH4)2PdCl4 | 13820-40-1 |
green
crystal |
37 |
| K634 | Palladium Chloride | PdCl2.2H2O | 7647-10-1 |
brown
powder |
60 |
| K635 | Palladium bromide | PdBr2 | 13444-94-5 |
violet
crystal |
40 |
| K636 | Palladium iodide | PdI2 | 7790-38-7 | black powder | 29.4 |
| K637 | (pi-allyl)Palladium(II)chloridedimer | [(pi-C3H5)PdCl]2 | 12012-95-2 |
yellow crystal |
58.2 |
| K638 | Trans-dichlorobis(acetonitrile)palladium(II) | trans-PdCl2(CH3CN)2 | 14592-56-4 | yellow powder | 41 |
| K639 | Potassium tetrachloropalladate | K2PdCl4 | 10025-98-6 | brown powder | 32 |
| K640 | Potassium hexachloropalladate | K2PdCl6 | 16919-73-6 | red powder | 27 |
| K641 | Bis(dibenzylideneacetone)palladium | (dba)2Pd | 32005-36-0 | reddish brown powder | 20 |
| K642 | Palladium black | Pd | 7440-05-3 | black powder | 99.95 |
|
HETEROGENEOUS
CATALYSTS |
|||||
|
Code |
Name |
Support Material |
Precious Metal
Content (wt%) |
||
| K681 |
Pd/C |
Active Carbon |
1% 5% 10% 20% |
||
| K682 |
Pd/SiO2 |
SiO2 |
1% 2% 5% 10% |
||
| K683 |
Pd/Al2O3 |
Al2O3 |
1% 5% 10% 20% |
||
| K684 | Pd(OH)2/C |
Active Carbon |
1% 5% 10% 20% |
||
| K685 | Pd/BaSO4 | BaSO4 |
1% 5% 10% 20% |
||
| K686 |
LINDLAR Pd/CaO3 |
CaO3 |
1% 5% 10% 20% |
||
|
Ru |
|||||
|
homogamous
catalyst |
|||||
|
Code |
Name |
Formula |
CAS |
Color & Form |
Precious
Metal Content (wt%) |
| K201 |
Ruthenium trichloride |
RuCl3 |
10049-08-8 |
brown powder |
49 |
| K202 |
Ruthenium trichloride |
RuCl3.nH2O |
14898-67-0 |
brownish black crystals | 40 |
| K203 |
Ruthenium
acetate |
Ru(OAc)x |
55466-76-7 |
black
powder |
47 |
| K204 |
Ruthenium oxide |
RuO2 |
12036-10-1 |
black
powder |
75 |
| K205 |
Ruthenium oxide
hydrate |
RuO2.nH2O |
32740-79-7 |
black
powder |
62 |
| K206 |
Tris(triphenylphosphine)Rutheniumdichloride |
RuCl2(PPh3)3 |
15529-49-4 |
reddish brown crystals | 10 |
| K207 |
(1,5-Cyclooctadiene)-dichloro Ruthenium |
Ru(COD)Cl2 |
50982-12-2 |
brown
powder |
35 |
| K208 |
Carbonyltris(triphenylphosphine)rhodium(I)dihydride |
RuH2(CO)(PPh3)3 |
25360-32-1 |
cream
powder |
11 |
| K209 |
TrisacetylacetonateRuthenium |
Ru(acac)3 |
14284-93-6 |
red powder |
25 |
| K210 |
Ammonium hexachloroRuthenate(IV) |
(NH4)2[RuCl6] |
18746-63-9 |
brown
powder |
31 |
| K211 |
Ammonium-nitrido-octachlorodiaquodiruthenate(IV) |
(NH4)3.Cl8H4NO2Ru2 |
27316-90-1 |
red powder |
34 |
| K212 |
Dichloro(p-cymene)ruthenium(II)
dimer |
Ru(C10H14)2Cl2 |
52462-29-0 |
brown crystals | 33 |
| K213 |
Ruthenium nitrosyl nitrate |
Ru(NO3)3.NO |
34513-98-9 |
reddish
brown powder |
30 |
|
|
|
|
|
|
|
|
HETEROGENEOUS
CATALYSTS |
|||||
|
Code |
Name |
Support Material |
Precious Metal
Content (wt%) |
||
| K281 |
Ru/C |
Active Carbon |
1% 5% 10% 20% |
||
| K282 |
Ru/SiO2 |
SiO2 |
1% 2% 5% 10% |
||
| K283 |
Ru/Al2O3 |
Al2O3 |
1% 5% 10% 20% |
||